Commercial product name: ACRIS 418
Product code: 27867

1. Identification of the product and of the company

Preparation date:
13.06.2003

Revision date:
05.09.2008

Commercial product name
ACRIS 418

Product type and use
Organic solvent solution of vinyl acetate/acrylic copolymer

Supplier
ICAP-SIRA Chemicals and Polymers SpA Via Corridoni,19 - 20015 Parabiago (Milano - Italy) Tel. (+ 39) 0331/496111 - Fax. (+ 39) 0331/495005 Capitale Sociale Euro 27.000.000 Interamente Versato Società soggetta all'attività di direzione e coordinamento di Perledo S.p.A. con sede in Parabiago (MI) Via Corridoni n.14

Emergency telephone number
(+39) 0331/496111 o (+39) 348/2313571

Other numbers of emergency
Centro Anti Veleni Ospedale Niguarda Milano +39 02-66101029

2. Hazards identification

Possible risk of harm to the unborn child Highly flammable Harmful by inhalation Possible risk of impaired fertility Vapours may cause drowsiness and dizziness Harmful : danger of serious damage to health by prolonged exposure through inhalation Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment

3. Composition/information on ingredients

Hazardous components
Contained substances are dangerous as per directive 67/548 EEC and further amendments or for which there are recognised exposure limits: Pentan-2,4-dione: 1-1,5% Symbol Xn R Phrases : 10-22 CAS 123-54-6 EINECS 204-634-0 CEE 606-029-00-0 Mixture of not aromatic hydrocarbon: 12-14% F N Xn R: 11-38-48/20-51/53-62 -65-67 Toluene: 29-31% Symbols: F-XN-Xi-cat3 R:11-38-48/20-63-65-67 CAS: 108-88-3 EINECS: 203-625-9 CEE: 601-021-00-3

4. First aid measures

Inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.

Skin contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes.

Eye contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion
Do not induce vomiting without medical advice.

5. Fire-fighting measures

Suitable extinguishing media
foam carbon dioxide (CO2) dry chemical

Specific methods
In the event of fire and/or explosion do not breathe fumes. Water mist may be used to cool closed containers.

6. Accidental release measures

Prevent product from entering drains. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Take up mechanically and collect in suitable container for disposal.

7. Handling and storage

Technical measures/Storage conditions
Store in original container.

Handling
Do not breathe vapours or spray mist.

Technical measures/Precautions
Provide adequate ventilation.

Storage
Keep at temperature not exceeding 35°C.

8. Exposure controls / personal protection

Respiratory protection
Breathing apparatus with filter.

Hand protection
protective gloves (EN 374)

Eye protection
safety glasses (EN 166)

Skin and body protection
lightweight protective clothing

Hygiene measures
When using, do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling the product.

National occupational exposure limits
50 ppm ( Toluene ) 50 ppm ( N.esano )

9. Phisical and chemical properties

Form
liquid

Colour
colourless

Odour
solvent

Boiling point/range
65-140°C

Density
0,95 Kg/lt about

Water solubility
insoluble closed cup

Flash point
-2 °C

10. Stability and reactivity

Stability
Stable under recommended storage conditions.

11. Toxicological Information

LD50/dermal/rabbit= >2000 mg/Kg Mixture of no-aromatic hydrocarbon LD50/dermal/rabbit= 12124 mg/Kg Toluene LC50/inhalation/rat= 4000 ppm - 4 h Toluene LD50/oral/mouse= >28700 mg/Kg Mixture of no-aromatic hydrocarbon LD50/oral/mouse= 5000 mg/Kg Toluene LC50/inhalation/rat= >20 mg/l 4 h Mixture of no-aromatic hydrocarbon

Vapours due to thermic decomposition
irritant

12. Ecological information

Should not be released into the environment.

13. Disposal considerations

Must be incinerated in a suitable incineration plant authorised under the Environmental Protection Act 1990.

14. Transport information

UN-NR: 1866 Class: 3 IMDG: 3 ICAO/IATA: 3 ADR/RID: 3 Packing group: II Prescriptions: 640 D EmS: F-E S-E

Further information for delivery note
Resin in solvent, flammable

15. Regulatory information

R Hazards
R62 - Possible risk of impaired fertility. R63 - Possible risk of harm to the unborn child. R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R11 - Highly flammable. R38 - Irritating to skin. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. R67 - Vapours may cause drowsiness and dizziness

S Hazards
S43 - In case of fire, use sand, dry chemical or alcohol-resistant foam. S61 - Avoid release to the environment. Refer to special instructions/Safety data sheets. S16 - Keep away from sources of ignition - No smoking. S21 - When using do not smoke. S25 - Avoid contact with the eyes. S33 - Take precautionary measures against static discharges. S36/37 - Wear suitable protective clothing and gloves. S60 - This material and/or its container must be disposed of as hazardous waste.

Hazards Labelling
F - Highly flammable Xn - Harmful

Contains
n-Hexane Toluene

Law provisions and regulations
European Regulations: Reg. 1907/2006; Dir. 67/548 CEE, Dir. 76/769 CEE, Dir. 1999/45 CEE and subsequent emendments.

16. Other information

Full text of the ( R ) risk phrases indicated at point 3 R65 - Harmful: it may cause damage to lungs in case of ingestion R62 - Possible risk of impaired fertility. R63 - Possible risk of harm to the unborn child. R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R10 - Flammable. R11 - Highly flammable. R22 - Harmful if swallowed. R38 - Irritating to skin. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. R67 - Vapours may cause drowsiness and dizziness The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.