Commercial product name: ACRIS 453
Product code: 28379

1. Identification of the product and of the company

Preparation date:
25.07.1989

Revision date:
30.04.2008

Commercial product name
ACRIS 453

Product type and use
Organic solvent solution of vinyl acetate/acrylic copolymer

Supplier
ICAP-SIRA Chemicals and Polymers SpA Via Corridoni,19 - 20015 Parabiago (Milano - Italy) Tel. (+ 39) 0331/496111 - Fax. (+ 39) 0331/495005 Capitale Sociale Euro 27.000.000 Interamente Versato Società soggetta all'attività di direzione e coordinamento di Perledo S.p.A. con sede in Parabiago (MI) Via Corridoni n.14

Emergency telephone number
(+39) 0331/496111 o (+39) 348/2313571

Other numbers of emergency
Centro Anti Veleni Ospedale Niguarda Milano +39 02-66101029

2. Hazards identification

Highly flammable Irritating to eyes Repeated exposure may cause skin dryness or cracking Vapours may cause drowsiness and dizziness

3. Composition/information on ingredients

Hazardous components
Contained substances are dangerous as per directive 67/548 EEC and further amendments or for which there are recognised exposure limits: Ethyl Acetate: 45-50% Symbol: F-XI R-Phrases: 11-36-66-67 CAS:141-78-6 CEE: 607-022-00-5 EINECS:205-500-4 Toluene: 0-2% Symbols: F-XN-Xi-cat3 R:11-38-48/20-63-65-67 CAS: 108-88-3 EINECS: 203-625-9 CEE: 601-021-00-3

4. First aid measures

Inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.

Skin contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes.

Eye contact
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Ingestion
Do not induce vomiting without medical advice.

5. Fire-fighting measures

Suitable extinguishing media
foam carbon dioxide (CO2) dry chemical

Specific methods
In the event of fire and/or explosion do not breathe fumes. Water mist may be used to cool closed containers.

6. Accidental release measures

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Take up mechanically and collect in suitable container for disposal.

7. Handling and storage

Technical measures/Storage conditions
Store in original container.

Technical measures/Precautions
Provide adequate ventilation.

Storage
Keep at temperature not exceeding 35°C.

8. Exposure controls / personal protection

Respiratory protection
Breathing apparatus with filter.

Hand protection
protective gloves (EN 374)

Eye protection
safety glasses (EN 166)

Skin and body protection
lightweight protective clothing

Hygiene measures
When using, do not eat, drink or smoke. Wash hands and face before breaks and immediately after handling the product.

National occupational exposure limits
400 ppm ( Ethyl Acetate )

9. Phisical and chemical properties

Form
liquid viscous

Odour
solvent

Boiling point/range
77°C. CA

Density
0,95 Kg/lt about

Water solubility
insoluble

Flash point
-4 °C closed cup

Explosivity limits in the air % in V/V:
Lower: 2,1 Higher: 11,5

10. Stability and reactivity

Stability
Stable under recommended storage conditions.

11. Toxicological Information

There are no toxicological data on the preparation. LD50/dermal/rabbit= > 18000 mg/Kg Ethyl Acetate LD50/oral/mouse= 5600 mg/Kg Ethyl Acetate LC50/inhalation/rat= 56 mg/l 4 h Ethyl Acetate

Vapours due to thermic decomposition
irritant

12. Ecological information

Should not be released into the environment.

13. Disposal considerations

Must be incinerated in a suitable incineration plant authorised under the Environmental Protection Act 1990.

14. Transport information

UN-NR: 1866 Class: 3 IMDG: 3 ICAO/IATA: 3 ADR/RID: 3 Packing group: II Prescriptions: 640 D EmS: F-E S-E

Further information for delivery note
Resin in solvent, flammable

15. Regulatory information

R Hazards
R11 - Highly flammable. R36 - Irritating to eyes. R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapours may cause drowsiness and dizziness

S Hazards
S 7 - Keep container tightly closed. S16 - Keep away from sources of ignition - No smoking. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33 - Take precautionary measures against static discharges. S24/25 - Avoid contact with skin and eyes.

Hazards Labelling
F - Highly flammable Xi - Irritant

Law provisions and regulations
European Regulations: Reg. 1907/2006; Dir. 67/548 CEE, Dir. 76/769 CEE, Dir. 1999/45 CEE and subsequent emendments.

16. Other information

Full text of the ( R ) risk phrases indicated at point 3 R65 - Harmful: it may cause damage to lungs in case of ingestion R63 - Possible risk of harm to the unborn child. R11 - Highly flammable. R36 - Irritating to eyes. R38 - Irritating to skin. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapours may cause drowsiness and dizziness The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.